1-Bromo-3-Methylbutane: An In-Depth Look

Historical Development of 1-Bromo-3-Methylbutane

Chemists have spent the better part of two centuries learning how to bend molecules to their will. 1-Bromo-3-methylbutane, also called isoamyl bromide, became a staple thanks to early organohalide research. Since the days when Auguste Cahours and others first isolated various brominated alkanes in the 19th century, researchers noticed that adding a bromine atom to a branched alkyl chain produced reliably reactive intermediates. This ability to functionalize carbon skeletons opened doors in both academic and industrial chemistry labs. The compound steadily found its place as a practical building block, riding on the back of advances in organic synthesis like the Grignard reaction or the Wurtz–Fittig reaction. Those methods drove the expansion of complex molecule assembly, with 1-bromo-3-methylbutane often serving as a key piece in the puzzle.

Product Overview

1-Bromo-3-methylbutane brings simple structure and usefulness to the table: a five-carbon chain with a bromine at one end, branching at the third carbon. The chain length and substitution pattern give it desirable reactivity for alkylation reactions. For people working in research or fine chemical production, this molecule feels like a reliable tool, ready for both routine syntheses and niche projects. Whether in a glass flask at a university or a scale-up rig at a chemical plant, its role as an alkylating agent remains clear-cut. Often found as a colorless, sometimes slightly yellowish liquid, the compound provides predictable performance for a range of transformations.

Physical and Chemical Properties

1-Bromo-3-methylbutane presents itself as a clear liquid with a boiling range around 116–118°C, and a density close to 1.17 g/cm³ at 25°C. These numbers line up with what one expects from similar alkyl bromides, making it easy to handle for those used to organic solvents. Its vapor is heavier than air, so spills or leaks in labs can create hazards at floor level. The molecule dissolves only sparingly in water, but it mixes well with common organic solvents such as ether, chloroform, or ethanol. Flammability requires attention, and its vapor can irritate the respiratory system, so basic chemical safety habits stay important.

Technical Specifications and Labeling

Commercial bottles usually come marked with detailed specifications, including assay (purity, usually >98%), water content, and residual acid content. Labels highlight the reagent’s chemical name, structural formula, batch number, and hazard statements. Signal words like “danger” or “warning” often feature, accompanied by standardized hazard pictograms showing health and fire risks. For labs aiming for reproducibility, knowing the stated assay prevents guesswork. Most suppliers include a safety data sheet (SDS), offering detailed information about safe handling, storage, disposal, and what to do in emergencies. That transparency allows researchers to make informed choices before working with the substance.

Preparation Method

Standard production relies on the conversion of the corresponding alcohol, 3-methyl-1-butanol (isoamyl alcohol), using hydrobromic acid or sodium bromide with sulfuric acid. The process involves heating the alcohol with the acid, causing substitution of the hydroxyl group by bromine through an SN1 or SN2 pathway depending on reaction conditions. Many chemists gain hands-on experience preparing small batches in an undergraduate lab, watching the phase separation as product distills away. In industry, continuous reactors handle larger volumes, with byproduct control and purification built into every step. Water washes, drying agents, and fractional distillation all play roles in ensuring the right quality ends up in the final bottle.

Chemical Reactions and Modifications

1-Bromo-3-methylbutane reacts easily with nucleophiles in substitution reactions, making it a reliable source for introducing the 3-methylbutyl group into other molecules. It works particularly well in the formation of Grignard reagents, providing access to branched carbon skeletons after reaction with magnesium metal in ether. The resulting magnesium bromide complex opens the door to further carbon-carbon bond formation, a crucial step in custom molecule synthesis. Beyond Grignard reactions, 1-bromo-3-methylbutane participates readily in Williamson ether synthesis, giving branched ethers valued in perfume and flavor chemistry. The reactivity of the bromide also allows transformation to a range of functional groups—amines via nucleophilic substitution with ammonia, or organolithium reagents using lithium metal. Each of these transformations ties into modern pharmaceutical and fine chemical manufacture.

Synonyms and Product Names

Over the years, this alkyl bromide picked up an array of synonyms: isoamyl bromide, isopentyl bromide, 3-methyl-1-bromobutane, or even 1-bromoisoamyl. Catalogs and chemical suppliers often use one name more than the others, depending on regional or industry preference. On packaging, labels maintain strict IUPAC conventions—1-bromo-3-methylbutane—and list registry numbers like CAS 3572-67-6 to avoid confusion. These alternate names reflect the connection to isoamyl alcohol and help people recognize the compound under various trade names.

Safety and Operational Standards

Working with 1-bromo-3-methylbutane calls for careful handling. Its volatility and pungent smell remind operators to stick with fume hoods and wear suitable personal protective equipment. Inhaling its vapor or letting it contact skin causes irritation. Chronic exposure has been linked to central nervous system effects in animals, so sealing containers tightly, using splash goggles, and double-gloving when handling spills increases safety. Storage should avoid sunlight, open flames, and temperature extremes—fire cabinets provide the right containment in most labs. Emergency response centers stress quick removal to fresh air and rinsing for skin or eye contact. Waste handled as halogenated organic solvent ensures proper environmental management.

Application Area

Industries use 1-bromo-3-methylbutane wherever branched alkyl chains need to be attached, especially in synthesis of pharmaceuticals, agrochemicals, and specialty flavors. The Grignard reaction route finds a natural home in drug discovery, enabling rapid construction of molecule libraries for biological screening. Flavor houses and fragrance formulators look to isoamyl derivatives for fruity and floral notes, and starting from this alkyl bromide simplifies mixing the right esters and ethers. In teaching labs, its use gives students exposure to practical aspects of substitution reactions and organic purification methods, reinforcing theory learned in textbooks. This combination of educational, industrial, and research uses keeps demand steady.

Research and Development

Ongoing research seeks new applications for 1-bromo-3-methylbutane, especially as chemists push for greener, more sustainable methods. Studies on using eco-friendly solvents or recyclable catalysts during transformations help cut down on hazardous waste. In pharmaceutical pipelines, the compound contributes to the synthesis of branched intermediates not easily accessible by alternate routes, giving companies a competitive edge through intellectual property. Universities publish papers on stereochemistry and mechanistic pathways, exploring how minor changes in precursor structure affect outcomes in multi-step syntheses. This cycle of publication and application sustains innovation not only for 1-bromo-3-methylbutane, but for many alkyl halides.

Toxicity Research

Toxicologists continue to investigate the health impact of short- and long-term exposure. Animal studies show that high doses cause discomfort, respiratory irritation, and neurological symptoms. These findings prompted stricter industrial exposure limits and spurred research into less toxic alternatives where substitution fits the end goal. Recent work looks at environmental breakdown pathways, monitoring how bromides persist in soil and water. Methods such as gas chromatography track trace levels in workplace air and in products, alerting health officials and ensuring compliance with safety regulations. Sharing data from toxicity research strengthens workplace practices and informs regulatory updates in the chemical industry.

Future Prospects

The drive toward cleaner chemistry will shape the way laboratories and factories use halogenated reagents like 1-bromo-3-methylbutane. Advances in reaction engineering may lower the waste produced during its preparation. Development of direct catalytic coupling approaches could sidestep the use of hazardous halides. Yet demand for branched alkyl intermediates won’t fade—biotechnology and medicinal chemistry trends favor such structures for improved drug metabolism. As researchers develop new routes to high-value molecules, they continue to draw inspiration and lessons from traditional compounds like 1-bromo-3-methylbutane. Companies exploring circular chemistry, waste minimization, and hazard reduction treat its use as both a challenge and an opportunity to innovate responsibly.



What is the molecular formula of 1-Bromo-3-Methylbutane?

Molecular Structure and Formula

Chemistry turns mysterious when you look at names like 1-Bromo-3-Methylbutane. Strip away the technical language, and you notice the pattern. The core of the name reveals the structure: a butane backbone (four carbons), a bromine attached to carbon one, and a methyl group attached to carbon three. Put that together, and you get C5H11Br as the molecular formula. This isn’t just trivia for students; the structure tells you a lot about how the molecule behaves in labs, factories, and even the environment.

Practical Reason for Importance

Working with organic chemicals has taught me that knowing the exact molecular formula is non-negotiable. Every reaction, every property—boiling point, solubility, toxicity—connects back to that formula. One mistake in a formula, and you could end up using the wrong chemical, wasting resources, or creating a hazard.

For companies making pharmaceuticals or plastics, precision matters even more. A formula like C5H11Br points to a molecule with hydrophobic tendencies and a reactive bromine atom. That knowledge shapes how people transport, store, and use it. Regulators rely on this information to draw up safety sheets and enforce laws that keep workers safe. A wrong or poorly communicated formula sets up a domino effect—legal trouble, accidents, missed targets for sustainability, all because the chain of information snapped at the start.

Real-World Consequences

Incorrectly reporting or reading a formula has led to mishaps both big and small. In university labs, I’ve watched as a single miswritten symbol sent experiments spiraling off script. On a larger scale, take the pharmaceutical sector—errors in reaction design could yield impurities or reduce effectiveness, sending products back to the drawing board and increasing costs. The stakes rise steeply with scale: environmental releases—like halogenated compounds—pose issues for soil and water when people don’t track every atom. C5H11Br contains bromine, which signals both special handling and waste disposal rules you can’t ignore.

Transparency and Trust

Scientists, manufacturers, and public health officials keep coming back to the same point: accuracy builds trust. If the formula doesn't match up with the substance, top-down confidence crumbles. That goes for researchers sharing data, regulatory agencies evaluating toxicology, or journalists reporting on a chemical spill. Everyone needs the same language and facts, and the molecular formula sits right at the center of that shared knowledge. Thousands of readers depend on reputable sources to maintain this standard, which means checking and rechecking every published structure. In the digital age, wrong information lingers and spreads, highlighting the responsibility to get the basics right.

Better Solutions for Learning and Sharing Information

More students now rely on digital platforms and open-access databases to get chemical data. Accurate, peer-reviewed sources online reduce mix-ups and make learning accessible. Professors and trainers can push for more visual teaching—model kits, apps, and 3D structures—so learners grasp structures faster. Fact-checking by independent experts before data hits public pages can filter out most errors. Open channels between academia, industry, and regulators keep everyone on the same page. Sharing not only formulas but also reliable background builds stronger foundations, whether in classrooms or commercial labs.

What are the common uses of 1-Bromo-3-Methylbutane?

Where You'll Find 1-Bromo-3-Methylbutane Working

Spend any amount of time in a chemistry lab, and you’ll see compounds with long, tongue-twisting names filling up shelves and cabinets. 1-Bromo-3-methylbutane often sits quietly among those, but it packs more use than its simple label suggests. This small molecule routinely crops up as a building block for other chemicals—something synthetic chemists rely on for piecing together new compounds, especially for pharmaceuticals and lab research. The bromo group on this molecule acts like a handle, ready for scientists to swap it out for just about anything else, opening doors for creativity in chemical synthesis.

One place this compound regularly proves itself is in the creation of specialty organic molecules. Because it serves as an “alkylating agent,” it helps researchers attach a four-carbon chain to other molecules. That’s important when designing ingredients for medicines or surfactants, where precise control over molecular shape matters. Take the pharmaceutical industry. Customizing molecular backbones starts with platform chemicals like 1-bromo-3-methylbutane. A chemist might need an isopentyl group—this is a classic go-to. Swapping out the bromine delivers that group onto other chemical frameworks, and you’ll see this same trick translating to new painkillers or disease-fighting drugs. Patented molecules often start life as little more than a smart substitution on a backbone—something this bromo compound really enables.

Rising Value in Industrial Synthesis

Labs aren’t the only ones making use of it. Larger operations put it to work on an industrial scale. If you’ve ever dealt with synthesizing flavors or fragrances, you’re probably familiar with the challenge of building the right carbon skeleton that holds the key aroma. This compound’s structure nestles perfectly for such modifications—giving chemists control to build molecules that mimic nature or create something new. Flavorists count on building blocks like this for consistent and predictable results, especially when natural extraction from rare plants can’t keep up with demand or runs too expensive.

I spent my grad school years helping prepare custom reagents for a major chemical catalog, and requests for alkylating agents like 1-bromo-3-methylbutane flowed in regularly. Most came from university labs or biotech startups developing their own processes, but a handful were for materials science research. If a polymer needs a specific side chain for flexibility or resilience, it often starts with these foundational molecules. Real ingenuity in modern chemistry often comes from these subtle substitutions and the tools that make them possible.

Safety and Environmental Responsibility

Handled the wrong way, 1-bromo-3-methylbutane reminds us just how quickly a routine day can shift. Exposure risks include skin and eye irritation, and vapor build-up carries hazards—even an experienced chemist needs good ventilation and protective gear. I’ve watched even seasoned scientists rush for the eyewash station after a slip, emphasizing the need for solid safety protocols. On the industrial scale, strict waste management is not just regulatory red tape; it protects workers and limits environmental harm.

Alternatives emerge as health and environment questions come into sharper focus. Greener synthetic strategies draw plenty of attention, striving to replace more hazardous reagents without sacrificing effectiveness. Investment in safer substitutes and robust environmental protections stays crucial—not just for regulatory compliance, but for keeping lab workers and local communities safe. Training programs and shared best practices go a long way to cut down on accidents and waste. In my experience, taking a few extra minutes to review procedures can make all the difference, especially with potent chemicals like this one.

Looking Forward: Smarter Chemistry

As green chemistry ideas keep spreading, the future sees chemists leaning on thoughtful design and safer replacements. Until then, 1-bromo-3-methylbutane keeps its spot as a powerful, reliable tool in the chemist’s toolkit—best used with care, respect, and a practical sense for both safety and sustainability.

What is the physical appearance and odor of 1-Bromo-3-Methylbutane?

Physical Look — More Than Meets the Eye

1-Bromo-3-Methylbutane flows out of the bottle with a consistency that’s easy to spot: clear, sometimes with a hint of colorlessness that looks just like someone poured out water. But don’t get fooled—one whiff or even just a glance at the label signals you’re dealing with a potent chemical. In many labs, a bottle of this compound never stays far from the shelves, especially in organic synthesis work. Those amber glass bottles lining the chemical storeroom often carry liquids with that same watery clarity, but it’s crucial never to judge by looks. A single drop can slip between gloved fingers and leave a slick residue behind. That slip tells you it’s not water.

Pouring it, you’ll notice it’s less viscous than many solvents but not quite as “runnable” as specialized hydrocarbons like hexane. It holds a certain slickness, unmistakable if you’ve ever used small-molecule bromides in practical chemistry. The clarity matches textbook photos, leaving little doubt about purity—until contamination introduces a haze, which can reveal storage problems or careless handling. Keeping it in tight-sealed bottles helps, especially since exposure to light or air might slowly degrade its fresh appearance over time.

Odor — Not Your Average Smell

Open the lid and you’ll pick up a strong, almost choking sharpness that marks many bromoalkanes. Having worked with halogenated compounds for years, the odor hits with more bite than simple alkanes, sharper and heavier. People sometimes try to compare it with cleaning fluids or industrial solvents, but that doesn’t do the experience justice. The pungency lingers in the air, sometimes burning at the nose—sharp, almost chemical-sweet in the way some lab smells burn their memory into your sinuses.

Even in ventilated labs, the scent leaks into the hallway, sparking conversation among chemists about proper fume hood practice. There’s good reason: inhalation comes with risk, from headaches to more serious health effects, given the toxicity of many organobromides. In handling, careful labeling cuts down on accidental exposure, and solid training helps avoid breathing it in. NIOSH and OSHA both classify this material as hazardous, with exposure limits set up for operator protection. The Material Safety Data Sheet lists both the acute nose-wrinkling odor and the risks associated, always reminding us that chemistry is no playground.

Why Appearance and Odor Matter in Real Labs

Recognition matters plenty once you step away from theory and touch real bottles. Lab safety hinges on being able to spot and identify substances correctly. I remember a training session early in my career where someone mistook a clear, nondescript liquid for a benign solvent—one small spill left a sharp chemical stench and made it clear that visual cues aren’t always enough. Being attuned to each nuance—the clarity, the thickness, the distinct odor—builds practical safety skills no textbook can ever replace.

Industry and university researchers rely on tight safety routines as well as technical knowledge. Good ventilation, use of tightly closed amber bottles, and immediate cleanup of spills all protect workers. Awareness can go further. Many labs place detailed warning signs and reminders near storage shelves. Institutions back this up with training and ongoing reminders to minimize exposure and reduce risks. Fast action in case of a leak and using supplied air respirators or well-fitted masks shows real-world experience counts for as much as lab theory.

Solutions for Safer Handling

Keeping 1-bromo-3-methylbutane out of the wrong hands starts with solid inventory tracking and staff education. Sealed, labeled containers get checked regularly for leaks or degradation. Recapping bottles right after use stops that sharp odor from escaping and protects against lingering airborne risks. Anyone tasked with transferring or disposing of this compound uses spill kits designed to neutralize organobromides, with all work done under fume hoods to reduce exposure. Those habits save time—and as memory of a sneezing fit or burning nose tells me, they preserve health as well.

How should 1-Bromo-3-Methylbutane be stored and handled safely?

Real Risks, Not Just Regulation

Dealing with 1-Bromo-3-Methylbutane feels a lot like working with other mid-level laboratory solvents — except the stakes get higher once you know where the trouble can start. This chemical sets off alarm bells not just because of its flammability, but because its vapors can mess with your lungs and skin. Over the years, I’ve learned to respect any substance eager to evaporate at room temperature, especially one that can sneak into the air and wind up where you don’t want it. That’s most of the reason rules shape how to store and handle it, but it’s the practical details that keep you healthy and the lab running smoothly.

Put It Away Like You Mean It

No one wants to hear another lecture about chemical shelves, but staying careful with 1-Bromo-3-Methylbutane matters in more ways than safety checklists suggest. Stick it in a cool, well-ventilated room, nowhere near sparks or sunny windows. Sparks don’t ask questions — I saw an old timer toast an entire bench by underestimating a single static zap during winter. Throw flammable liquids in a proper flammables cabinet, and double-check that this cabinet breathes well. Missing that point leaves too much vapor hanging around, inviting bigger problems.

Forget about repurposing water bottles or soda flasks. Always use tightly-sealed glass or HDPE containers graded for chemicals. I once saw a careless swap to a weak plastic jug lead to a slow leak, which nobody caught until a headache blossomed across the room. Label everything, bold letters, clear hazard symbols. It’s not just for the comfort of regulators — it saves you from reaching for the wrong stuff in a hurry and saves your coworkers from nasty surprises.

Don’t Trust Gloves That Lie

Relying on old gloves or masks makes as much sense as driving with bald tires. 1-Bromo-3-Methylbutane seeps right through the wrong materials and burns fast enough to flame out small talk. Splash goggles and nitrite or neoprene gloves work best; latex fails to stand up to repeated contact. Change out gloves after spills, and don’t wipe things down with bare hands “just for a second.” Everyone who cuts corners here eventually winds up with irritated skin or the familiar sting up their nose from vapors. I’ve seen too many promising researchers take risks, banking on being lucky, but chemistry doesn’t care about luck.

Ventilation: Not Optional

Open the fume hood long before bringing out the bottle, not as an afterthought. I watched a close call unfold when a colleague figured they’d just open and measure quickly outside of one. The sweet, irritating scent crept through the lab. A few folks felt the effects within minutes, showing once again that even the “tough” can’t muscle their way through exposure to halogenated solvents. Relying on open windows won’t cut it. If your setup doesn’t include a solid exhaust, get the boss to invest or put the chemical on the “do-not-use” list until that happens.

What Happens If Things Go Wrong?

Quick access to eyewash stations and showers can spell the difference between a funny story and an ER visit. Spills call for absorbent pads built for organics, not towels snagged from under the sink. Don’t forget about proper disposal. Pouring leftovers down the drain leads to fines and bigger headaches when the local water treatment folks trace a chemical signature back to your bench. Look up your local chemical waste facilities and use them every single time.

Keeping Track for the Long Run

Solid records help you catch leaks in stock, spot patterns in use, and remind you to check dates on old bottles. Inventory tracking wasn’t my favorite job, but after cleaning up a spill from an expired jug, the value made sense. Rotate inventory, keep stock low, and always stagger larger orders with actual demand. The safer the storage, the fewer risky surprises show up. Taking shortcuts might save time in the short run, but chemicals like this repay that gamble in accidents and ruined research.

What are the potential health hazards or risks associated with 1-Bromo-3-Methylbutane?

Why Recognizing Chemical Risks Matters

Most people never hear about chemicals like 1-Bromo-3-methylbutane until their daily routine gets close to the worlds of labs, warehouses, or industrial work. My first encounter came in a small organic synthesis lab, where the scent alone clued me in to its volatility. I didn’t think much about it until a safety officer rattled off a list of possible health effects—rash, coughing, headaches—if treated carelessly.

Folks working with this compound, or even near it, face specific risks. Even short, accidental exposure can trigger an irritating response in the eyes, throat, or lungs. It doesn’t matter if you're a seasoned chemist or a new hire running errands in storage—a splash or a whiff can prompt burning and watery eyes, a fit of coughing, or trouble breathing. These symptoms feel real and can ruin a day at work if you’re not prepared.

How Skin and Lungs Take the Hit

Once, after a late night in the lab, I noticed a chemical burn on the edge of my glove. The culprit turned out to be a small drip of 1-Bromo-3-methylbutane. This compound slips through latex and light nitrile, and even brief contact leaves behind redness, itching, or a rash—sometimes before you know what's happening. Data from the U.S. National Library of Medicine backs up these stories: contact or inhalation can result in dermatitis or respiratory irritation. The material evaporates easily at room temperature, so leaks or spills don’t stay put.

Repeated exposure can stir up more severe problems, with people reporting persistent asthma-like symptoms. Lab animal studies also point toward damage to liver or kidney function from long-term exposure, although a clear link in humans remains less well documented. I’ve seen colleagues recover after a week away from the lab—but some still battled lingering coughs for months.

Systemic Effects and the Brain

At times, inhalation brings on headaches, dizziness, and even confusion—especially if ventilation in the workspace falls short. I remember an afternoon spent tracking a malfunctioning fume hood, noticing how exhaustion and grogginess crept up on everyone nearby. The chemical’s smell—sharp, almost sweet—serves as its only warning. One study I read in the Archives of Toxicology described neurological symptoms in exposed workers, ranging from mild forgetfulness to slower reaction times. The possibility of chronic effects like this deserves more attention and better reporting, especially in facilities with poor controls.

Handling Practices That Can Stop Trouble Before It Starts

Common-sense habits keep risks lower. Fume hoods, sturdy gloves (butyl or neoprene, not latex), and splash goggles matter more than most realize. A strict culture around labeling and secondary containment prevented many emergencies at a busy supplier where I did a summer internship. Shower stations and eyewash fountains won’t fix the problem, but they cut injuries down when fast response counts. I’ve seen cases where workers relaxed their guard, skipped PPE, or missed a regular glove change—almost always leading to accidents that could’ve been sidestepped.

The hard part lies in keeping safety procedures interesting and fresh, so nobody forgets in the rush of a busy shift. Companies should invest real dollars into clear signage, mandatory refresher training, and robust incident reporting with follow-ups. Bringing in an outside health and safety consultant once or twice a year uncovered risks we’d missed from our own routines.

What’s at Stake

1-Bromo-3-methylbutane comes with risks that aren’t always obvious if you only glance at an old chemical label. First-hand experience and official data both point toward real hazards for skin, lungs, and even long-term neurological health. Recognizing these dangers leads to better habits, stronger controls, and a workplace that values health from top to bottom.

1-Bromo-3-Methylbutane
1-Bromo-3-Methylbutane
1-Bromo-3-Methylbutane
Names
Preferred IUPAC name 2-Bromo-3-methylbutane
Other names 1-Bromisoamyl
1-Bromo-3-methylbutane
Isoamyl bromide
Isoamylbromid
3-Methyl-1-bromobutane
Pronunciation /waɪˈbrəʊməʊ θriː ˈmɛθɪlˈbjuːteɪn/
Identifiers
CAS Number 107-82-4
3D model (JSmol) CCCC(C)Br
Beilstein Reference 1721207
ChEBI CHEBI:81344
ChEMBL CHEMBL169782
ChemSpider 50706
DrugBank DB01912
ECHA InfoCard 100.003.878
EC Number 202-876-1
Gmelin Reference 6967
KEGG C06735
MeSH D000628
PubChem CID 10940
RTECS number EJ4200000
UNII 5802E8D4SN
UN number UN2342
CompTox Dashboard (EPA) DTXSID3048835
Properties
Chemical formula C5H11Br
Molar mass 137.04 g/mol
Appearance Colorless liquid
Odor penetrating odor
Density 1.218 g/mL
Solubility in water Insoluble
log P 2.4
Vapor pressure 2.6 mmHg (at 25 °C)
Acidity (pKa) pKa ≈ 50
Magnetic susceptibility (χ) -71.5e-6 cm³/mol
Refractive index (nD) 1.437
Viscosity 2.89 mPa·s (20 °C)
Dipole moment 2.30 D
Thermochemistry
Std molar entropy (S⦵298) 258.6 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -119.6 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) –3430.7 kJ/mol
Hazards
GHS labelling GHS02, GHS07
Pictograms GHS02, GHS07
Signal word Warning
Hazard statements H226, H315, H319, H335
Precautionary statements P210, P243, P280, P303+P361+P353, P305+P351+P338, P370+P378
NFPA 704 (fire diamond) 1-2-0
Flash point 44 °F (NTP, 2022)
Autoignition temperature 230 °C
Lethal dose or concentration LD₅₀ (oral, rat): 2,400 mg/kg
LD50 (median dose) LD50 (median dose) = 760 mg/kg (rat, oral)
NIOSH RQ6300000
PEL (Permissible) Not established
REL (Recommended) 5 ppm
IDLH (Immediate danger) Not established
Related compounds
Related compounds 1-Bromobutane
1-Bromo-2-methylpropane
1-Chloro-3-methylbutane
1-Iodo-3-methylbutane
3-Methyl-1-pentanol